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Cruise
Log: Wednesday, March 31, 2004
Contributor: David Ho Lamont Doherty Earth Observatory As Mike Harvey mentioned in the previous web log, we had decided to re-infuse what remains of our patch with more iron and tracers. This started last night. Complicated procedures often seem to go more smoothly the second time around, and the second iron/tracer infusion was no exception. Unlike the first time, where it took many days (and a detour) to have a working GC/TCD (gas chromatograph thermo conductivity detector), Andrew Marriner and Peter Hill were able to get the GC/TCD up and running after less than one hour. The instrument is used to detect the high concentration of 3He and SF6 in the tanks. On board the ship, we have two identical large (ca. 4000 L) tanks for tracer saturation. Tank #1 was used for the initial infusion. Tank #2 had been saturated with SF6 along with tank #1, so all that needed to be done was to inject the 3He. Since 3He costs more per unit weight than saffron, we had to be careful in handling it and make sure that we did not lose it to the atmosphere. Andrew and I were in charge of this, and it went off without a hitch. We created a headspace in the tank with 3He, and turned on a pump to circulate the tracer through a gas diffuser hose in the water in order to dissolve the tracer. With just the right amount of water, tracer, internal pressure, and pumping rate, we were able to create the perfect symphony of bubbles right below the intake of the circulation pump. Andrew described it as "poetry in motion." Our original intention was to bubble for 20 minutes. However, with 20 minutes approaching, things were going so well that we did not want to turn the pump off. I suppose it is akin to turning off free cable television, with the fear that it will not come on again. But alas, Andrew and I both realize that all good things must come to an end so one of us flipped the switch.
My main role on the voyage is the sampling of 3He. Combined with SF6, these two tracers will allow us to calculate how rapidly gases transfer between the atmosphere and ocean. Knowledge of this is crucial to predictions of climate change, since the ocean acts as a large store for greenhouse gases such as carbon dioxide. Samples for 3He are taken in copper tubes, closed off by stainless steel pinch-off clamps and stored for measurement in the laboratory by mass spectrometry. See http://www.ldeo.columbia.edu/etg for more information about the 3He extraction and measurement. Next Day >>
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