A
buoy similar to the one on which the ozone instrument will be mounted
This
buoy was used by WHOI scientists for studies of aerosols in the marine
boundary layer (click
here for the
"Sea-Aer" web page). The
ozone instrument will be sharing a buoy with many of the instruments
from the Sea-Aer project, as well as basic meteorological equipment,
allowing for simultaneous measurements in the same location.
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Excess tropospheric
ozone poses serious health risks to humans and other species. This
ozone originates from both natural processes and anthropogenic sources.
The predominant anthropogenic source stems from the burning of fossil
fuels and biomass, and as one would expect, recent increases in the
combustion of these materials have led to increased ozone pollution.
A serious question concerning ground-level ozone is what happens after
it is produced. With a lifetime on the order of a few weeks, it can
travel significant distances in the free troposphere. For instance,
ozone levels on Cape Cod tend to increase when winds are from the
southwest, bringing in pollution from the Mid-Atlantic states.
Downwind effects on ozone concentrations become more difficult to
understand as distances increase. This is particularly true for intercontinental
ozone transport. Research has shown a correlation between increased
fossil fuel emissions in Asia and tropospheric ozone in the western
United States (Jacob et al., 1999). Similar data has been found suggesting
that the eastern United States impacts tropospheric ozone levels in
parts of Western Europe (e.g. Parrish et al., 1993).
Our current understanding of global tropospheric ozone is based predominantly
on atmospheric models and land-based ozone measurements throughout
the globe. In the U.S., the EPA AIRS
network of monitoring stations for ozone, other gases, and aerosols
provides reasonably dense coverage over land. However, virtually no
long-term experimental data have been collected directly over the
oceans, leaving more than 70% of Earth's surface without regular observations.
Continuously measuring ozone over large bodies of water from planes,
balloons, or ships is prohibitively expensive. However, long-term
continuous measurements are necessary, since ozone and other pollution
events are variable and episodic. Ocean buoys equipped with reliable,
autonomous ozone sensors that are capable of functioning for extended
periods of time without human intervention could fill this "data
gap."
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