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WHOI Funding and Awards --> Cecil H. and Ida M. Green Technology Innovation Awards --> 2005 Abstracts

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Abstracts of 2005 Cecil H. and Ida M. Green Technology Innovation Awards

A New Broadband, Low Cost, High Resolution Side-Scan Sonar for Small AUV's
Dezhang Chu and Tom Austin

As small AUV’s become more popular, the need grows for high quality, low cost sensors that are specifically designed to support the specific size, power, and cost constraints of these vehicles. This proposal combines a newly developed ultra-miniature high frequency sonar transceiver with a novel broadband acoustic transducer design to significantly improve the imaging quality possible from a very low cost sonar imaging system.

Broadband sonar system can be used for a variety of acoustic applications in ocean explorations, ranging from seafloor mapping, to sub-bottom profiling, and to water column mapping. However, to fabricate wide-band acoustic transducers with flat and uniform spectra is a challenging task, especially when a consistent spectrum is required in applications involving broadband acoustic arrays. A new approach is proposed to construct broadband transducers using a spectrum-matching method, in which the frequency response or power spectrum will be designed to match the inherent frequency characteristics of the PZT ceramics. With this approach, the spectrum of the transducer can be controlled simply by the geometric shape of the ceramics relative to the known spectrum of a reference transducer, and hence a wide band and smooth spectrum can be achieved. By incorporating the state of art electronics developed previously and a side-scan sonar array consisting of the broadband transducer elements developed through this proposal, we will build and test a broadband, low cost, and high resolution side-scan sonar mounted on a small AUV (REMUS).


Helical Turbine Generators for Moored Applications
Donald Peters and Matthew Naiman

Power for oceanographic instrumentation on moorings can be derived from a number of sources. For surface moorings, a combination of solar panels and storage batteries is a common and effective way to generate and store power. Commercially available wind generators can also be used for power generation. However, both solar panels and wind generators are vulnerable to damage on a surface buoy, and in some locations lack of sun limits the effectiveness of solar panels. At high latitudes in particular, harsh conditions, icing, and low sunlight availability make solar and wind power poor choices for long-term power generation. The purpose of this proposal is to study the viability of Gorlov helical turbines as an alternative power generation source on oceanographic moorings.

Gorlov helical turbines are actuated by the flow of water, and are novel in that their direction of rotation is always the same, regardless of incoming flow direction. On surface moorings, an element on the mooring some distance from the surface experiences not only the ambient horizontal flow from wind and tidal currents, but also an oscillating vertical flow produced by the heave of the surface buoy. A properly oriented helical turbine could derive power from all of these flow components simultaneously. One goal of the proposed work is to develop a mounting arrangement for these turbines that makes the best use of the available flow, and to study ways of enhancing that flow. The other goal is to investigate techniques for extracting electrical power from the turbines, in a way that is both mechanically simple and electrically efficient.


Developing Compound-Specific Stable Bromine Isotope Measurements
C. Reddy, L. Ball, R. Nelson, S. Sylva

Brominated organic compounds (BOCs) are important molecules involved in climate change, human and marine mammal health, and chemical ecology. We believe that studying the subtle changes in the ratios of the stable bromine isotopes, 79Br and 81Br, will be an effective tool and add to the field. To achieve the latter, this proposal requests funds to build an interface between a gas chromatograph (GC) and an inductively coupled plasma mass spectrometer (ICP-MS), which will allow us to measure the bromine isotope ratios on individual compounds. We will also develop standards and perform initial experiments. This novel approach will be useful by many scientists interested in the source, transport, and fate of BOCs in the environment. We hope to use this support to provide enough data for an initial publication as well as a much larger NSF-style proposal.


Raman Spectroscopy for In Situ Mineralogical Analyses
Sheri N. White and Meg Tivey

In-situ sensors capable of real-time measurements and analyses in the deep ocean are necessary to fulfill the potential created by the development of autonomous, deep-sea platforms such as AUVs and cabled observatories. Raman spectroscopy is an optical technique which is capable of in situ molecular identification of solids, liquids, and gases, and is well suited to extreme environments. At present, it is not possible to identify the chemical composition of minerals in situ. Raman spectroscopy has been used successfully for mineral identification in the laboratory. The development of a sea-going Raman system capable of deployment on an ocean observatory or AUV will allow the in situ analysis of minerals that are deposited and precipitated at hydrothermal vent sites. This will provide insights into processes occurring in the subsurface which affect ocean chemistry.

The goal of this proposal is to perform the background analyses and research necessary to obtain funding for the development of a small-scale laser Raman spectrometer specifically designed for in situ mineralogical analyses in the deep ocean. Many rocks and minerals found in the deep ocean (e.g., basaltic components and hydrothermal minerals) are Raman active. Laboratory measurements (both at WHOI and in collaboration with scientists in NH) will be made to determine the optimal characteristics for a deep-sea mineralogical Raman system. These include excitation wavelength, spectral range, and sensitivity. Commercial “hand-held” Raman systems will also be investigated. The long-range goal is development of a mineralogical Raman system small enough to be deployed on an AUV.


A Re-Determination of the 14C Half-Life
Mark Roberts

In 1960, the Nobel Prize in chemistry was awarded to W.F. Libby for “his method to use carbon-14 for age determination in archaeology, geology, geophysics, and other branches of science”. Integral to Libby’s work was the determination of the 14C half-life. Today, the accepted half-life of 14C is 5700 years ± 30 years (National Nuclear Data Center, Brookhaven National Laboratory). This value is the weighted average of values obtained from specific activity measurements. Recently, based on apparent systematic trends and offsets in the radiocarbon calibration curve (cf., Reimer, 2004), questions have been raised as to the validity of the ‘accepted’ 14C half-life (Broecker, 2005a and 2005b). A significant shift in the 14C half-life impacts not only archeology and paleo-oceanography, but also modern estimates of planetary scale thermohaline overturning rates and abyssal biogeochemical fluxes. Moreover, such a change requires revision of estimated cosmogenic nuclide production rates over the past 50,000 years. Although there are no specific reasons to doubt the current 14C half-life value, an alternative approach to determining its value would be an important and conclusive test of Broecker’s hypothesis. We propose a novel method to measure the 14C half-life that does not rely upon a specific activity measurement. Using a high-energy accelerator, we will implant a known number of 14C ions into a silicon based beta spectrometer. The beta spectrometer will then be removed from the accelerator and operated in a ‘self-count’ mode to determine the number of implanted 14C atoms that decay in a given time. With precise knowledge of the initial number of atoms implanted and the resulting number of 14C decays per unit time, the half-life of 14C can be determined.


Toward an Image-Based Cell Sorter for Plankton Research at Ocean Observatories
Robert J. Olson

We propose to explore a way of combining these approaches, so that individual cells can be sorted and then manipulated to provide information beyond identification. In this way we can study more directly the mechanisms behind the species distributions we observe. The need for this type of sampling capability was recently highlighted at an international National Ocean Partnership Program (NOPP) workshop on marine ecogenomics. Specifically, we propose here to use miniature solenoid valves to sort microplankton cells automatically, by momentarily redirecting a sample stream through a re-usable nylon mesh, where the cells will be exposed to a fluorescent DNA stain and then imaged by a CCD camera. Our longer term goal is to incorporate this laboratory prototype into our new submersible imaging flow cytometer, where real-time identification of individual cells will provide the basis for sorting decisions.


Preparation of Carbon Dioxide for Radiocarbon Analysis from Marine Dissolved Organic Carbon
Li Xu and Ann P. McNichol

Radiocarbon (14C) is a powerful tracer for global carbon cycling studies. The advent of accelerator mass spectrometry (AMS) 25 years ago revolutionized radiocarbon analysis and opened the field to many more research areas. Radiocarbon studies of all the carbon pools in the ocean are providing insights into the transfer of carbon in the ocean. Dissolved organic carbon (DOC) plays an important role in carbon cycling in marine environment and studies of its radiocarbon content will provide valuable information in identifying its sources and estimating the turnover rate of organic carbon in the marine system. Currently, the method to measure 14C in DOC is not routinely available in most AMS labs, including the National Ocean Sciences Accelerator Mass Spectrometry Facility (NOSAMS). We propose to develop a method to analyze 14C in marine DOC, in order to benefit carbon cycle researchers, both inside and outside WHOI.


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