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Click on
image to enlarge. |
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| CTD is ascending
to the ocean surface
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| … and coming
on board where Wendy Richardson (left), Doug
Sieberg (middle), and Bon van Hardenberg (right)
are recovering and guiding it onto the deck
of the ship. |
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| Linda White
and Naoaki Uzuka collect water samples for
chemical analyses. |
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| Naoaki Uzuka
(left) analyses O-18s and Celine Gueguen (right)
filters water samples for chlorophyll analyses. |
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| Doug Sieberg
(left) prepares the CTD rosette and Linda
White analyses water samples for nutrients. |
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| Left:
Bongo net sampling - vertical tows - provides
information regarding population density,
species composition and DNA and molecular
structure of Arctic zooplankton. Right: Camille
and Linda collect zooplankton samples. |
Cruise - 2003 Dispatches
Calendar
Dispatch 11 - August 28-30,
2003 By Andrey Proshutinsky
Chemistry from the surface to the bottom
Throughout the cruise, our chemistry team (from
the Institute of Ocean Science in Canada and the
International Arctic Research Center in the USA)
has been measuring seawater properties and obtaining
seawater samples for chemical analysis, most recently
along 75°N latitude. In the following text,
Fiona Mclaughlin (who communicates with us every
day from Sidney, B.C.) and Valerie Forsland explain
the major goals and methods of water analysis being
conducted on this expedition:
We are using a 24-bottle CTD/rosette to collect
water column samples to investigate the origin and
age of waters found in the Canada Basin. The rosette
is lowered to the seafloor and then, as it is pulled
upward, each 10 L bottle is closed individually
to provide a sample from 24 different depths
reaching from the surface to as deep as 3800 m.
When the rosette is brought back onboard the ship,
a team of scientists from IOS and IARC are at-the-ready,
anxious to get started with the sub-sampling.
At a typical station there may be as many as 20
different sample containers to be filled from each
10 L bottle, ranging in size from a 10 ml test tube
to a 10 L carboy. The water from each rosette bottle
is analyzed for a number of geochemical constituents
and each tells a different story and helps us to
understand how the large scale atmosphere-ocean
system works. Some of the geochemical tracers are
being analyzed onboard ship and some are returned
to laboratories in Canada, Japan and the US.
One of the many questions we are asking on this
expedition is whether the strength and location
of the Beaufort Gyre affects the storage of freshwater.
And, from an oceanographic point of view, freshwater
refers to more than river or ice-melt water. For
example we will be calculating the freshwater content
at every station by integrating the difference in
salinity we measure by comparing it to a reference
salinity of S=34.8. In addition to salinity, we
are also collecting samples for barium and oxygen
isotope (δ18O) analysis. Barium
tells us whether surface waters originate from the
Mackenzie River, the largest Canadian river that
flows into the Arctic Ocean; δ18O
tells us how much of the freshwater is due to the
melting of ice; and it is important to distinguish
between these two different sources of freshwater
when investigating questions about climate change.
We are also investigating the carbon cycle and how
greenhouse gases such as carbon dioxide are dissolved
in the ocean and buried for periods of time. We
are collecting alkalinity and total carbon dioxide
samples from 4 different regions of the Canada Basin
and δ13C in surface waters at all
stations to investigate the role that the Canada
Basin is playing in the global climate system. Plankton
are also another part of the carbon cycle
the organic part and we are filtering waters
of the upper ocean to find out how much life is
present.
We are interested in knowing how old waters of the
Canada Basin are and by old we mean how long
it has been since they were last in contact with
the atmosphere. Samples for CFC (freon11,12
refrigerant), helium, tritium (3H) and
δ14 C measurements provide information
on different timescales 2- 65 years for CFCs
and He/3H and hundreds of years for δ14
C. Waters of the deep Canada Basin are believed
to be 400-600 years old, dating back to the time
of Columbus. We are curious to discover if deep
waters in the Canada Basin are all this old.
Geochemical tracers help us identify the source
and circulation pathways of the two principal water
masses found in the Canada Basin. Pacific-origin
waters are fresher and contain more nutrients -
silicate, nitrate, and phosphate - than the warmer
and saltier Atlantic-origin waters. Atlantic-origin
waters also carry higher values of radionuclides
such as 129I and 137Cs than
Pacific-origin waters. These radionuclides are by-products
of nuclear re-processing plants in France and England
and enter the Canada Basin via the Norwegian Coastal
Current and Fram Strait. We are interested in where
the boundaries between Pacific and Atlantic-origin
waters are situated and how these locations vary
over time.
Various phytoplankton species coexist in the ocean
but they are roughly characterized by size. We are
investigating the vertical distribution of the phytoplankton
in 3 size fractions (0.7-2um, 2-10um and >10um)
in the Canadian Basin. As well, bongo net sampling
vertical tows - provides information regarding
population density, species composition and DNA
and molecular structure of Arctic zooplankton.
Dissolved organic carbon (DOC), categorized into
humic substance, carbohydrates, lipids, proteins
and other minor components, is also important in
the carbon cycle. A portion of total DOC, which
absorbs light (CDOM), is used as a tracer for land/shelf
interaction. CDOM and DOC are measured to track
freshwater in the Beaufort Gyre.
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